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ChemInform Abstract: Baker′s Yeast Mediated Mono-Reduction of 1,3-Cyclohexanediones Bearing Two Identical C(2) Substituents.

✍ Scribed by Zhi-Liang Wei; Zu-Yi Li; Guo-Qiang Lin


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Baker′s Yeast-Media
✍ R. TANIKAGA; Y. OBATA; K. KAWAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Baker's Yeast-Mediated Reduction of Cyclohexanones Containing a Nitro or a Sulfonyl Group at C-3. -The title compounds (Ia)-(Ic) undergo Baker's yeast mediated reduction with high enantioselectivity. The remote nitro and sulfonyl groups, in contrast to alkyl and sulfenyl groups, may play an importa