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ChemInform Abstract: Baker′s Yeast-Mediated Reduction of Cyclohexanones Containing a Nitro or a Sulfonyl Group at C-3.

✍ Scribed by R. TANIKAGA; Y. OBATA; K. KAWAMOTO

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199806055

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✦ Synopsis

Baker's Yeast-Mediated Reduction of Cyclohexanones Containing a Nitro or a Sulfonyl Group at C-3.

-The title compounds (Ia)-(Ic) undergo Baker's yeast mediated reduction with high enantioselectivity. The remote nitro and sulfonyl groups, in contrast to alkyl and sulfenyl groups, may play an important role in binding to an enzyme. -(TANIKAGA, R.; OBATA,

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