Asymmetric Syntheses of Both Enantiomers of α-Benzylserine and . alpha.-Carboxymethylserine. -The (R)-and (S)-enantiomers of the title serines (VI) and (VIII) are prepared starting from acetol (I) via an intramolecular asymmetric Strecker synthesis. This method uses the L-or D-amino acids (II), res
ChemInform Abstract: Aziridine Mediated Asymmetric Synthesis of α-Benzylserine and α-n-Butylserine.
✍ Scribed by Franklin A. Davis; Yulian Zhang; Ashwin Rao; Zhijun Zhang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Aziridine 2-Carboxylate Ester Mediated Asymmetric Synthesis of α-Alkyl β-Amino Acids. -Highly stereoselective reductive ring opening of the N-tosylaziridines (II) with LiAlH4 followed by oxidation of the syn-amino alcohols (III) provides an efficient entry to the asymmetric synthesis of αmethyl β-am
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v