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ChemInform Abstract: Aziridine 2-Carboxylate Ester Mediated Asymmetric Synthesis of α- Alkyl β-Amino Acids.

✍ Scribed by F. A. DAVIS; G. V. REDDY; C.-H. LIANG

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199743205

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✦ Synopsis

Aziridine 2-Carboxylate Ester Mediated Asymmetric Synthesis of α-Alkyl β-Amino Acids. -Highly stereoselective reductive ring opening of the N-tosylaziridines (II) with LiAlH4 followed by oxidation of the syn-amino alcohols (III) provides an efficient entry to the asymmetric synthesis of αmethyl β-amino acids, important synthons of natural products. -(DAVIS, F.

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