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ChemInform Abstract: Asymmetric Synthesis of the Japanese Beetle Pheromone via Boronic Esters.

✍ Scribed by William C. Hiscox; Donald S. Matteson


Publisher
John Wiley and Sons
Year
2001
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Asymmetric Synthesi
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Asymmetric Synthesis of Serricornin via Boronic Esters. -The title compound (XIII), the pheromone of the cigarette beetle, is synthesized from chiral (II) in 59% overall yield. -(MATTESON, D.

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A Highly Enantioselective and Diastereoselective Synthesis of Cyclobutanes via Boronic Esters. -Deprotection of enantiopure boronate (II) with LDA provides a spirocyclic boronate which rearranges in high enantiopurity to the cyclobutanone (IV) on treatment with catalytic MgBr 2 . Interestingly, no c