ChemInform Abstract: Asymmetric Synthesis of (S)-Arylalkanols by Microbial Reduction.
β Scribed by K. NAKAMURA; T. MATSUDA; A. OHNO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Synthesis of Sphinganine by Means of Modified Asymmetric Borane Reduction. -A modified asymmetric borane reduction of the ester (I) and the related silyl ether (V) are described. Thus, reduction of the ester yields mainly the threo compound, whereas the silyl ether affords the desir