## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
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ChemInform Abstract: Asymmetric Synthesis of Quaternary Centers. Total Synthesis of (-)-Malyngolide.
β Scribed by Barry M. Trost; Weiping Tang; Joerg L. Schulte
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 29 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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The Synthesis of Quaternary Carbon Centers Through Cyclialkylations. -Treatment of the conjugated dienone (I) with Lewis acid at low temperature results in Diels-Alder reaction including the arene moiety to yield a hydrophenanthrene (II) with a newly created quaternary carbon. At higher temperature