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ChemInform Abstract: Asymmetric Synthesis of erythro-8-O-4′-Neolignan Machilin C.

✍ Scribed by Yamu Xia; Liang Chang; Yining Ding; Bin Jiao

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Synthesi
ChemInform Abstract: Asymmetric Synthesis of the Natural erythro-(1R,2S)-8-O-4′-Neolignan Myrislignan.
✍ Y. Xia; Wei Wang 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

## Abstract The synthesis of myrislignan (VI) is achieved in twelve steps from vanillin (I) with a total yield of 10% involving two key steps: preparation of the enantiopure threo alcohol (III) of predictable stereochemistry by dihydroxylation, and inversion of the absolute configuration at the C‐8