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ChemInform Abstract: Efficient Asymmetric Synthesis of Pumiliotoxin C via Intramolecular [4 + 2] Cycloaddition.

✍ Scribed by Wolfgang Oppolzer; Elmar Flaskamp; Lothar W. Bieber

Publisher
John Wiley and Sons
Year
2001
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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Efficient Asymmetric Synthesis of Pumili
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An efficient asymmetric synthesis in nine steps of natural (Γ€)-pumiliotoxin C (1), a decahydroquinoline alkaloid found in the skin of Central American frog species, is presented. The enantiomerically pure starting material (S)-norvalinol (3), obtained from commercial (S)-norvaline, was cyclized in a

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v