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ChemInform Abstract: Asymmetric Synthesis of (+) and (-) trans-2,6-Dimethylpiperidines.

โœ Scribed by S. FREVILLE; M. BONIN; J.-P. CELERIER; H.-P. HUSSON; G. LHOMMET; J.-C. QUIRION; V. M. THUY

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of Unnatural 6ฮฑ-trans-2-Oxaisocephams and ฮด1(6)-2-Oxaisocephems. -Azetidinone (III), derived from dithiyl substituted azetidinone (I), undergoes intramolecular cyclization at room temperature to give stereoselectively the title compounds (IV) and (V), which could act as pr