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ChemInform Abstract: Asymmetric Synthesis of an Isoxazolidine Nucleoside Analogue of Thymine Polyoxin C.

✍ Scribed by P. MERINO; S. FRANCO; F. L. MERCHAN; T. TEJERO

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Asymmetric Synthesis of an Isoxazolidine Nucleoside Analogue of Thymine Polyoxin C.

-The first total synthesis of the isoxazolidine amino acid nucleoside analogue (VI) is based on the stereoselective nucleophilic addition of the silyl ketene acetal (II) to the enantiopure N-benzyl nitrone (I) as the key step.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of Thymine Polyoxin C Using an Allylic Trifluoroacetimidateβ€”Trifluoroacetamide Rearrangement.
✍ Anqi Chen; Eric J. Thomas; Peter D. Wilson πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 2 views

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