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ChemInform Abstract: Asymmetric Synthesis of 1,1′-Bis(1-hydroxyalkyl)metallocenes and Their Derivatization to the Novel Chiral Metallocenes with C2 Symmetry.

✍ Scribed by M. WATANABE


Book ID
112029639
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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BMPD, a Novel C 2 -Chiral 1,3-Diketone Ligand; Synthesis and Application to an Asymmetric Catalytic Reaction. -A BMPDyttrium complex is found to be an efficient catalyst for the asymmetric silylcyanation of aldehydes. Aromatic aldehydes, except those with electronwithdrawing groups, show good to ex