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ChemInform Abstract: Asymmetric Synthesis of 1-Deoxy-8,8a-di-epi-castanospermine.

✍ Scribed by S. F. MARTIN; H.-J. CHEN; V. M. LYNCH

Book ID
112023163
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
26
Category
Article
ISSN
0931-7597

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A new and efficient enantioselective total synthesis of the title deoxycastanospermine derivative has been developed, based on amino acid and b-ketophosphonate chemistry, as well as employment of internal asymmetric induction for the creation of the new chiral centers proved successful. With proper