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Asymmetric Synthesis of 1-Deoxy-8,8a-di-epi-castanospermine

✍ Scribed by Martin, Stephen F.; Chen, Hui-Ju; Lynch, Vincent M.

Book ID
121260254
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
344 KB
Volume
60
Category
Article
ISSN
0022-3263

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A new and efficient enantioselective total synthesis of the title deoxycastanospermine derivative has been developed, based on amino acid and b-ketophosphonate chemistry, as well as employment of internal asymmetric induction for the creation of the new chiral centers proved successful. With proper