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ChemInform Abstract: Asymmetric Reduction of 2-Chloro-3-oxo Esters by Transfer Hydrogenation.

✍ Scribed by Jinjin Bai; Shifeng Miao; Yun Wu; Yawen Zhang


Publisher
John Wiley and Sons
Year
2012
Weight
27 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The reduction is accomplished by using Noyoriβ€²s Ru(cymene)‐TsDPEN catalyst.


πŸ“œ SIMILAR VOLUMES


Asymmetric Reduction of 2-Chloro-3-oxo E
✍ Jinjin Bai; Shifeng Miao; Yun Wu; Yawen Zhang πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 99 KB

## Abstract Asymmetric reduction of 2‐chloro‐3‐oxo esters was achieved by catalytic transfer hydrogenation using [RuCl~2~(__p__‐cymene)](__S__,__S__)‐TsDPEN as the chiral catalyst and HCOOH‐Et~3~N as the hydrogen source. Moderate to good yields (up to 85%) and good enantioselectivities (up to 98% _

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v