ChemInform Abstract: Asymmetric Michael Addition of Aldehydes to Nitroolefins Catalyzed by L-Prolinamide Derivatives Using Phenols as Co-Catalysts.
✍ Scribed by Yan-Qin Cheng; Zheng Bian; Ya-Bing He; Fu-She Han; Chuan-Qing Kang; Zhao-Lun Ning; Lian-Xun Gao
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
## Abstract A new chiral catalyst is presented for the asymmetric Michael addition of ketones to nitroolefins.
## Abstract Among a range of L‐proline‐derived lactams and amides, spirocyclic lactams (I), (II) and amide (III) possess the best catalytic activity in the title Michael addition of aldehydes towards β‐nitrostyrenes (IV).