ChemInform Abstract: Asymmetric Intramolecular Radical Vinylation Using Enantiopure Sulfoxides as Temporary Chiral Auxiliaries.
โ Scribed by Benedicte Delouvrie; Louis Fensterbank; Emmanuel Lacote; Max Malacria
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Alkylidene-substituted cyclopentane derivatives are formed in high enantiomeric purity by the reaction shown below. A highly diastereoselective radical cyclization is followed by elimination of a ฮฒ-sulfinyl radical. Interestingly, the addition of the Lewis acid methylaluminum bis(2,6-di-tert-butyl-4
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