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ChemInform Abstract: Asymmetric Hydrogenation of Enamides with Rh-BisP* and Rh-MiniPHOS Catalysts. Scope, Limitations, and Mechanism.

✍ Scribed by Ilya D. Gridnev; Masaya Yasutake; Natsuka Higashi; Tsuneo Imamoto

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Hydrogen
ChemInform Abstract: Asymmetric Hydrogenation Catalyzed by (S,S)-R-BisP*-Rh and (R,R)-R-MiniPHOS Complexes: Scope, Limitations, and Mechanism.
✍ Ilya D. Gridnev; Yoshinori Yamanoi; Natsuka Higashi; Hideyuki Tsuruta; Masaya Ya πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Asymmetric Hydrogenation Catalyzed by (S
Asymmetric Hydrogenation Catalyzed by (S,S)-R-BisPast;-Rh and (R,R)-R-MiniPHOS Complexes: Scope, Limitations, and Mechanism
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A new class of chiral C 2 -symmetric bis-(trialkyl)phosphine ligands has been prepared and used in Rh(I)-catalyzed asymmetric hydrogenation reactions. The ligands, 1,2-bis(alkylmethylphosphino)ethanes 1 aΒ±g (abbreviated as BisP\*, alkyl = tbutyl, 1-adamantyl, 1-methylcyclohexyl, 1,1-diethylpropyl, c