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ChemInform Abstract: Asymmetric Hydroformylation of Allylic Alcohols Catalyzed by Rh(I)—(R,S)-BINAPHOS.

✍ Scribed by K. NOZAKI; W. LI; T. HORIUCHI; H. TAKAYA


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Hydrofor
✍ T. HORIUCHI; T. OHTA; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex. -Optically active β,γ-unsaturated aldehydes are obtained in high regio-and enantioselectivities from dienes like (II) and (VI) by the title reaction with chiral (R,S)-BINAPHOS-Rh(I) complex as ca