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ChemInform Abstract: Asymmetric Conjugate Addition of Nitromethane to Enones Catalyzed by Chiral N,N′-Dioxide—Scandium(III) Complexes.

✍ Scribed by Liwei Wang; Qi Zhang; Xin Zhou; Xiaohua Liu; Lili Lin; Bo Qin; Xiaoming Feng


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

A simple to handle and highly efficient N,N′‐dioxide scandium(III) catalyst is developed for the asymmetric conjugate addition of nitromethane to chalcone analogues.


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Asymmetric Conjugate Addition of Nitrome
✍ Liwei Wang; Qi Zhang; Xin Zhou; Xiaohua Liu; Lili Lin; Bo Qin; Xiaoming Feng 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB 👁 2 views

The catalytic conjugate addition of nitroalkanes to a,b-unsaturated ketones is one of the most important processes in organic synthesis, [1, 2, 3] since the corresponding products are very useful intermediates for the synthesis of a variety of more elaborate structures, such as amino alkanes, amino