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ChemInform Abstract: Asymmetric Catalytic Hydrosilylation of Ketones with Triethoxysilane Using a Chiral Binaphthol-Titanium Complex.

✍ Scribed by H. IMMA; M. MORI; T. NAKAI

Book ID
112042262
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Catalyti
ChemInform Abstract: Asymmetric Catalytic Cyanosilylation of Aldehydes Using a Chiral Binaphthol-Titanium Complex.
✍ M. MORI; H. IMMA; T. NAKAI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Asymmetric Catalytic Cyanosilylation of
Asymmetric Catalytic Cyanosilylation of Aldehydes Using a Chiral Binaphthol-Titanium Complex
✍ Maki Mori; Hironori Imma; Takeshi Nakai πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 478 KB

The asymmetric cotalytic cyanosilylationof oliphaticaldehydes with Me3SiCN using (R)-BINOL-Ti(O-i-Pr)2 m an arymmem"c precakdyst is shown to proceed smoothly in dichloromethane to ~ford the cyanohydrinsin rekdvely high enantiose!ectivity (up @ 75~oee). @1997 Elsevier ScienceLtd. Recently,much inter