ChemInform Abstract: Asymmetric Allylation of Aldehydes Catalyzed by Substoichiometric Amounts of Chiral Phosphoramides.
β Scribed by K. ISEKI; Y. KUROKI; M. TAKAHASHI; Y. KOBAYASHI
- Book ID
- 112039138
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Chiral phosphoramides prepared from (S)-proline were used to catalyze the allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes in good enantioseleetive yields. Phosphoramides 4d and 4m gave chiral homoallylic alcohols and their enantiomers, respectively, with similar levels
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