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ChemInform Abstract: Asymmetric Addition of α-Hetero-Disubstituted Aldehydes to Vinyl Sulfones; Formation of Highly Functionalized Tetrasubstituted Carbon Centers.

✍ Scribed by Adrien Quintard; Alexandre Alexakis

Publisher: John Wiley and Sons
Year: 2010
Weight: 51 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201044081

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✦ Synopsis

Abstract

The title reaction proceeds rapidly and in high enantioselectivities due to the increased acidity of the hydrogen α‐ to the carbonyl group.

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