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ChemInform Abstract: Arylation of 8-Acetoxyoctalenone in a Nickel-Catalyzed Coupling Reaction with Lithium Arylborates.

✍ Scribed by Yuichi Kobayashi; Michiko Ito

Publisher
John Wiley and Sons
Year
2001
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Arylation of 8-Acetoxyoctalenone in a Ni
Arylation of 8-Acetoxyoctalenone in a Nickel-Catalyzed Coupling Reaction with Lithium Arylborates
✍ Yuichi Kobayashi; Michiko Ito πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 259 KB πŸ‘ 2 views

In order to find a suitable organometallic compound and a catalyst for the arylation of 8-acetoxyoctalenone 4 (a stereoisomeric mixture of 4Ξ± and 4Ξ²), phenylation was first investigated with PhZnX (7: X = Cl; 8: X = Br)/Pd or Ni cat., PhSnBu 3 (9)/Pd cat. and LiCl, and [PhB(Bu)(OCHMeCH-MeO)]Li (10a)

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