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Arylation of 8-Acetoxyoctalenone in a Nickel-Catalyzed Coupling Reaction with Lithium Arylborates

✍ Scribed by Yuichi Kobayashi; Michiko Ito

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
259 KB
Volume
2000
Category
Article
ISSN
1434-193X

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✦ Synopsis

In order to find a suitable organometallic compound and a catalyst for the arylation of 8-acetoxyoctalenone 4 (a stereoisomeric mixture of 4α and 4β), phenylation was first investigated with PhZnX (7: X = Cl; 8: X = Br)/Pd or Ni cat., PhSnBu 3 (9)/Pd cat. and LiCl, and [PhB(Bu)(OCHMeCH-MeO)]Li (10a)/Ni cat. Borate 10a provided the desired prod- [a]

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