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ChemInform Abstract: Application of a Novel Directing Effect in an Organocopper/Orthoester Reaction to the Synthesis of Deuterium Labeled Unsaturated Esters.

✍ Scribed by J. C. SHATTUCK; A. SVATOS; C. M. BLAZEY; J. MEINWALD

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199751084

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✦ Synopsis

Application of a Novel Directing Effect in an Organocopper/Orthoester Reaction to the Synthesis of Deuterium Labeled Unsaturated Esters.

-For biosynthetic studies on carboxylic acids in carabid beetles, deuterium labeled methacrylates (IV), tiglates (VIII) and senecioates ( XI) are prepared using organocopper-alkyne coupling reactions.

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