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ChemInform Abstract: Anomalous Dakin—West Reactions of Secondary α-Amino Acids with Trifluoroacetic Anhydride

✍ Scribed by Masami Kawase; Michitaka Hirabayashi; Setsuo Saito

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: An Anomalous Dakin—
ChemInform Abstract: An Anomalous Dakin—West Reaction of N-Carbamate Substituted Prolines and Trifluoroacetic Anhydride.
✍ M. KAWASE; M. HIRABAYASHI; H. KOIWAI; K. YAMAMOTO; H. MIYAMAE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

An Anomalous Dakin-West Reaction of N-Carbamate Substituted Prolines and Trifluoroacetic Anhydride. -The title reaction of proline derivatives, like (I) and (V), with anhydride (II) leads to the corresponding dihydropyrroles (III) and (V). A mechanism of this unexpected reaction is discussed. The st