ChemInform Abstract: Diquinane Synthesis
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K. SEKI; W. KIYOKAWA; H. HASHIMOTO; T. UYEHARA; M. UENO; T. SATO
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Article
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2010
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John Wiley and Sons
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Diquinane Synthesis Based on Anionic (1, 3) Sigmatropic Rearrangements of an Oxy-Cope System Incorporated in the Bicyclo(3.2.1)oct-6-ene Framework. -Treatment of 2-vinylbicyclooctenols (I) and (V) with KH in an appropriate solvent results in the formation of the (5-5) fused-ring compounds (II) and (