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ChemInform Abstract: An Unexpectedly Stable Chiral Hydrido-Solvent Complex of Ru(II): A Mechanistic Link in the Enantioselective Hydrogenation of Pyrones.

โœ Scribed by A. CURRAO; N. FEIKEN; A. MACCHIONI; R. NESPER; P. S. PREGOSIN; G. TRABESINGER

Book ID
112041407
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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An Unexpectedly Stable Chiral Hydrido-So
An Unexpectedly Stable Chiral Hydrido-Solvent Complex of RuII: A mechanistic link in the enantioselective hydrogenation of pyrones. Preliminary communication
โœ Antonio Currao; Nantko Feiken; Alceo Macchioni; Reinhard Nesper; Paul S. Pregosi ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 291 KB ๐Ÿ‘ 1 views

We have shown, separately, that heterolytic hydrogen activation by Ru(OAc),(l) in the presence of HBF, occurs readily at room temperature with 1 atm. of H,; however, for high yields of 2 the conditions given in the experimental part are best.