✦ LIBER ✦
An Unexpectedly Stable Chiral Hydrido-Solvent Complex of RuII: A mechanistic link in the enantioselective hydrogenation of pyrones. Preliminary communication
✍ Scribed by Antonio Currao; Nantko Feiken; Alceo Macchioni; Reinhard Nesper; Paul S. Pregosin; Gerald Trabesinger
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- German
- Weight
- 291 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
We have shown, separately, that heterolytic hydrogen activation by Ru(OAc),(l) in the presence of HBF, occurs readily at room temperature with 1 atm. of H,; however, for high yields of 2 the conditions given in the experimental part are best.