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ChemInform Abstract: An Unexpected Acid-Catalyzed Rearrangement of the Tricyclic System of Vinigrol to the Fusoxysporone Skeleton.

✍ Scribed by J.-F. DEVAUX; I. HANNA; J.-Y. LALLEMAND; T. PRANGE


Book ID
112034430
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: The Alkylation of a
✍ M. Teresa Barros; Anthony J. Burke; Christopher D. Maycock πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 2 views

The Alkylation of a Novel Acetal Derived from (2R,3R)-(+)-Tartaric Acid: An Unexpected Rearrangement. -Unexpected base-induced rearrangement of the chiral bis-acetal (IV) gives optically active dioxolane (V) accompanied by the two dioxanes (VI) and (VII). The product distribution depends on the equ