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ChemInform Abstract: An Efficient Synthesis of Antibiotic (-)-A26771B.

✍ Scribed by Yuichi Kobayashi; Hiroki Okui

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
31
Category
Article
ISSN
0931-7597

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Total Synthesis of Antibiotic Karnamicin B1. -The reaction of the furan derivative (I) with bromine in MeOH gives a bromo-methoxyfuran (III) instead of the normal dimethoxyfuran. Successful ring-transformation into the trihydroxy pyridine derivative (V) provides the base for the first total synthes