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ChemInform Abstract: Total Synthesis of Antibiotic Karnamicin B1.

✍ Scribed by K. UMEMURA; K. WATANABE; K. ONO; M. YAMAURA; J. YOSHIMURA

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Total Synthesis of Antibiotic Karnamicin B1.

-The reaction of the furan derivative (I) with bromine in MeOH gives a bromo-methoxyfuran (III) instead of the normal dimethoxyfuran. Successful ring-transformation into the trihydroxy pyridine derivative (V) provides the base for the first total synthesis of the novel antifungal karnamicin B1 (IX). -(UMEMURA, K.;

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