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ChemInform Abstract: An Efficient Synthesis of 2-Diazo-2-(trimethylsilyl)ethanols and Their Application to Pyrazole Synthesis.

โœ Scribed by Yoshiyuki Hari; Susumu Tsuchida; Ryosuke Sone; Toyohiko Aoyama


Publisher
John Wiley and Sons
Year
2008
Weight
31 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of Stable
โœ C.-H. LAI; Y.-L. SHEN; C.-C. LIAO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

## Synthesis of Stable Bromo-Substituted Masked o-Benzoquinones and Their Application to the Synthesis of Bicyclo[2.2.2]octenones. -Oxidation of the brominated phenol (II) in the presence of dienophiles generates adducts (V) via a masked o-benzoquinone. Debromonation of the adducts gives the bicy