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ChemInform Abstract: An Efficient Synthesis of 2-Cyclopentenones from γ-Ketoaldehyde Acetals Using Lithium Trimethylsilyldiazomethane. Its Application to the Synthesis of Trichodenone C (XXI).

✍ Scribed by Atsushi Sakai; Toyohiko Aoyama; Takayuki Shioiri


Publisher
John Wiley and Sons
Year
2000
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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Ester from Aldehyde Using (1-Ethoxyvinyl)lithium and Its Application to the Syntheses of Thymine Polyoxin C and Uracil Polyoxin C. -Starting from the known aldehyde (I), derived from D-ribose, a short synthesis to the key synthon (IV) is presented. The latter is subsequently converted to the title