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ChemInform Abstract: An Efficient Protocol for Sharpless-Style Racemic Dihydroxylation.

✍ Scribed by Jason Eames; Helen J. Mitchell; Adam Nelson; Peter O'Brien; Stuart Warren; Paul Wyatt

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
30
Category
Article
ISSN
0931-7597

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An Efficient Synthesis of (-)-Pestalotin and Its Enantiomer Using Sharpless Asymmetric Dihydroxylation. -The title compound (IV), a gibberellin synergist isolated from a phytopathogenic fungus Pestaltia cryptomeriaecola, is prepared using Sharpless asymmetric dihydroxylation as the key step. A simi