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ChemInform Abstract: An Efficient, One-Pot Synthesis of Fosfomycin Dialkyl Esters from (R)-2-Tosyloxypropanal.

โœ Scribed by Tadashi Hanaya; Yuichi Nakamura; Hiroshi Yamamoto

Publisher
John Wiley and Sons
Year
2008
Weight
28 KB
Volume
39
Category
Article
ISSN
0931-7597

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An Efficient One-Pot Synthesis of Dialkyl 2,5-Dihydrofuran-2,3dicarboxylates Mediated by Vinyltriphenylphosphonium Salt. -Functionalized 2,5-dihydrofurans (III) (9 examples) are prepared in fairly good yields by PPh 3 -mediated reaction of dialkyl acetylenedicarboxylates (I) with 2-hydroxyketones (I