ChemInform Abstract: An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and Its Salts in Aqueous DMSO.
โ Scribed by L. G. MENCHIKOV; A. V. VOROGUSHIN; O. S. KORNEVA; O. M. NEFEDOV
- Book ID
- 112030460
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Hydrolysis of alkyl halides in the presence of copper and its salts in aqueous DMSO (molar ratio organohalide:CuSO 4 ร5H 2 O:DMSO:H 2 O = 1:1:10ยฑ20:12ยฑ25) at 100ยฑ117 8C gives alcohols in high yields. Aryl halides containing no activating substituents are inert under the reaction conditions.
Hypervalent Iodine in Synthesis. Part 24. A Facile Method for the Preparation of Arylsulfinic Esters: Oxidation of Disulfides or Thiophenols by Phenyliodine(III) Bis(trifluoroacetate) in the Presence of Alcohols. -The oxidative reaction of disulfides (I) and thiophenols (IV) occurs readily in a sin