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ChemInform Abstract: An Asymmetric Synthesis of (+)-Grandisol (VI), a Constituent of the Aggregation Pheromone of the Cotton Boll Weevil, via a Kinetic Resolution

✍ Scribed by David P. G. Hamon; Kellie L. Tuck


Publisher
John Wiley and Sons
Year
2001
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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## A Concise Asymmetric Synthesis of the Pheromone 1-Methylcyclohex-2-enol (IV) via a "Merged Substitution-Elimination Reaction". -The title compound (III) is prepared from cyclohexene (I) via Sharpless asymmetric dihydroxylation using AD-mix-Ξ², tosylation and an unexpected elimination reaction.