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ChemInform Abstract: An Antimalarially Active Cyclic Peroxy Ketal.

✍ Scribed by G. H. POSNER; H. O'DOWD

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Functional Transfor
ChemInform Abstract: Functional Transformation of Aldehydes and Ketones via Homolytic Induced Decomposition of Unsaturated Peroxy Acetals and Peroxy Ketals.
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The induced decomposition of the unsaturated peroxy acetal (IV) in the presence of CCl 4 or ethyl iodoacetate leads to its chloro-or iododecarbonylation with good yields. This reaction is also applied to the monoperoxy ketal (VIII) and the diperoxy ketal (X) of cyclohexanone. The title decomposition