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ChemInform Abstract: Amino Alcohol Effects on the Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones in Propan-2-ol.

✍ Scribed by J. TAKEHARA; S. HASHIGUCHI; A. FUJII; S. INOUE; T. IKARIYA; R. NOYORI

Book ID: 112032305
Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199622072

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## Abstract The chiral amino amide **3** was derived from L‐proline and used for the [RuCl~2~(__p__‐cymene)]~2~‐catalyzed asymmetric transfer hydrogenation of prochiral ketones performed in water. Moderate to good chemical selectivities (up to 95% yield) and enantioselectivities (up to 90% ee) were