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ChemInform Abstract: Amino Alcohol Coordination in Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones.

โœ Scribed by Danielle G. I. Petra; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Kees Goubitz; Arjen M. Van Loon; Johannes G. de Vries; Hans E. Schoemaker

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
31
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES

Amino Alcohol Coordination in Ruthenium(
Amino Alcohol Coordination in Ruthenium(II)-Catalysed Asymmetric Transfer Hydrogenation of Ketones
โœ Daniรซlle G. I. Petra; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Kees Goubitz; ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 293 KB ๐Ÿ‘ 2 views

The nature of ruthenium-amino alcohol precursors in the aminoethane (1) coordinates through two nitrogen atoms, was structurally characterised by X-ray diffraction (8). -catalytic cycle of asymmetric hydrogen transfer reactions was studied using two C 2 -symmetrical tetradentate ligands (1 and Based

Chiral amino amides for the ruthenium(II
Chiral amino amides for the ruthenium(II)-catalyzed asymmetric transfer hydrogenation reaction of ketones in water
โœ Jincheng Mao; Jun Guo ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 119 KB

## Abstract The chiral amino amide **3** was derived from Lโ€proline and used for the [RuCl~2~(__p__โ€cymene)]~2~โ€catalyzed asymmetric transfer hydrogenation of prochiral ketones performed in water. Moderate to good chemical selectivities (up to 95% yield) and enantioselectivities (up to 90% ee) were