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ChemInform Abstract: Alkali Metal Hydride or Aqueous Hydroxide Induced Conjugate Addition of Trimethylsilyl Enol Ethers to Enones. A Convenient Alternative to Lewis Acid Mediated Reaction.

✍ Scribed by V. M. SWAMY; A. SARKAR

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199820060

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Alkali metal hydride or aqueous hydroxid

Alkali metal hydride or aqueous hydroxide induced conjugate addition of trimethylsilyl enol ethers to enones. A convenient alternative to Lewis acid mediated reaction

✍ Vishwanath M. Swamy; Amitabha Sarkar 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 152 KB

Conjugate addition to enones by enolates derived from baseqnduced cleavage of O-Si bond of trimethylsilyl enol ethers, yields 1,5-dicarbonyl compounds in good yields.