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ChemInform Abstract: Alkali Enolates of Unsymmetrical Ketones from Silyl Enol Ethers. Highly Regioselective Aldol Reactions Dependent on the Nature of the Cation.

✍ Scribed by P. DUHAMEL; D. CAHARD; Y. QUESNEL; J.-M. POIRIER

Book ID
112035224
Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Heck Reactions Star
ChemInform Abstract: Heck Reactions Starting from Silyl Enol Ethers β€” A Simple One-Pot Nonaflationβ€”Coupling Procedure for the Synthesis of 1,3-Dienes.
✍ M. WEBEL; H.-U. REISSIG πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 2 views

Heck Reactions Starting from Silyl Enol Ethers -A Simple One-Pot Nonaflation-Coupling Procedure for the Synthesis of 1,3-Dienes. -Silyl enol ethers (I) and (VIII) react with perfluorinated butanesulfonyl fluoride in the presence of catalytic amounts of Bu 4 NF. The resulting nonaflates are directly