ChemInform Abstract: Addition of TMS-Substituted Oxiranyl Anions to Acylsilanes. A Highly Stereoselective Approach to Tetrasubstituted (Z)-β-Hydroxy-α-TMS Silyl Enol Ethers.

✍ Scribed by Zhenlei Song; Leizhou Kui; Xianwei Sun; Linjie Li

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 38 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201125186

✦ Synopsis

Abstract

The sequential addition/Brook rearrangement/epoxide opening process proceeds with high stereoselectivity.