ChemInform Abstract: A Highly Stereoselective Approach to Tetrasubstituted (E)-β-Hydroxy Silyl Enol Ethers by Addition of Aryl-Substituted Oxiranyl Anions to Acylsilanes.

✍ Scribed by Cheng Wang; Zubao Gan; Ji Lu; Xia Wu; Zhenlei Song

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 30 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201134175

✦ Synopsis

Abstract

A sequential addition/1,2‐Brook rearrangement/epoxide‐opening process allows the synthesis of the desired synthons.