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ChemInform Abstract: Addition of Silyl Enol Ethers to Imidazoles and Thiazoles in the Presence of Alkyl Chloroformate.

✍ Scribed by T. ITOH; M. MIYAZAKI; H. HASEGAWA; K. NAGATA; A. OHSAWA


Book ID
112037609
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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Addition Reaction of Imidazoles and Thia
✍ Takashi Itoh; Michiko Miyazaki; Kazuhiro Nagata; Akio Ohsawa πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 205 KB

AbstractÐSilyl enol ethers and ketene silyl acetals reacted with imidazole, thiazole, and their benzo derivatives in the presence of an alkyl chloroformate to give 2-substituted imidazolines and thiazolines in good yields via the intermediacy of unstable N-acylated quaternary salts of azoles. In add