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Addition Reaction of Imidazoles and Thiazoles with Silyl Enol Ethers in the Presence of Alkyl Chloroformate

โœ Scribed by Takashi Itoh; Michiko Miyazaki; Kazuhiro Nagata; Akio Ohsawa

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
205 KB
Volume
56
Category
Article
ISSN
0040-4020

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โœฆ Synopsis

AbstractรSilyl enol ethers and ketene silyl acetals reacted with imidazole, thiazole, and their benzo derivatives in the presence of an alkyl chloroformate to give 2-substituted imidazolines and thiazolines in good yields via the intermediacy of unstable N-acylated quaternary salts of azoles. In addition, it was found that silyl enol ethers formed in situ were also useful for the reaction to afford the adducts only by simple sequential addition of ยฎve commercially available reagents.

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