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ChemInform Abstract: Addition of Azoles and Amines to Unsymmetrical Fumaric Esters.

✍ Scribed by P. ZADERENKO; M. C. LOPEZ; P. BALLESTEROS

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199705065

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✦ Synopsis

Addition of Azoles and Amines to Unsymmetrical Fumaric Esters.

-The nucleophilic addition takes place preferentially at the more sterically hindered side. This behavior is present in all azoles and more relevant in the bulkiest fumaric ester (IIc). The results are interpreted in terms of semiempirical AM1 MO calculations. -(ZADERENKO, P.; LOPEZ, M. C.;

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