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Regioselectivity for the Michael Addition of Thiols to Unsymmetrical Fumaric Derivatives.

✍ Scribed by Akio Kamimura; et al. et al.; et al. et al.


Publisher
John Wiley and Sons
Year
2004
Weight
235 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The first intramolecular nucleophilic addition of a thiol to a fullerene double bond is reported. Whereas the reaction of cysteine (**4**) or cystine (**11**) with formaldehyde and [60]fullerene in chlorobenzene at reflux afforded the new compound **10** bearing a thiazolidine moiety fu